Chemistry


Chapter : 7. Periodic Classification of Element

Features of the modified version of Mendeleev's Periodic Table

Features of the modified version of Mendeleev's periodic table :
1. Groups into subgroups : Each group of this periodic table is further divided into two subgroups A and B. The properties of elements within a subgroup resemble more markedly but they differ from those of the elements of the other subgroups. For example., lithium (Li), sodium (Na), potassium (K), etc., of subgroups IA have close resemblance of properties but they have hardly any resemblance to the coinage metals (Cu, Ag and Au) of subgroup IB.
Mendeleev allowed the subgroups to be represented within the same group.
2. Prediction of errors : This periodic table could predict errors in the atomic masses of some elements on the basis of their position in the periodic table. For example, when the periodic table was published, the experimental value of the atomic mass of beryllium (Be) we was supposed to be 13.65 and its valency, 3. So, the position of Be should have been somewhere else, but Mendeleev placed it at its appropriate position on the basis of its properties. He further suggested that the atomic mass of Be needed correction. Mendeleev predicted its atomic mass to be 9.1 and valency, 2. Latter investigations proved him right.
Similarly, the atomic mass of uranium was corrected from 120 to 240. Corrections were also made in the atomic masses of gold, platinum, etc.
3. Predictions of properties of higher to undiscovered element : We know that Mendeleev classified the elements in order of their increasing atomic masses. However, this order had to be ignored at some places to make sure that the elements with similar properties fell in the same group. In doing so, he left some vacant places in the table. These vacant places were kept reserved for elements not discovered till then. Mendeleev was confident that these elements would be discovered later and they would occupy these vacant places. Not only this, he also predicted the properties of these undiscovered elements on the basis of this study of his the properties of the neighboring elements. Amazingly, when the missing elements of Mendeleev's periodic table were discovered subsequently, their properties were found to be very similar to those predicted by Mendeleev.
The elements scandium, gallium and germanium were not known in 1871 but their existence was predicted by mendelev. He named these elements as eka-boron, eka-Aluminium and eka silicon when these elements were discovered, they were named scandium, gallium and germanium respectively and their properties were found to be in good agreement with those predicted by Mendeleev. Properties of ka-aluminium (predicted by Mendeleev) and those of the gallium (discovered later) are given in table.

Considering its atomic mass, titanium (Ti) should have been placed below aluminium in the periodic table, but Mendeleev placed is below silicon (Si) because the properties of titanium were similar to those of silicon. Thus, a gap was left below aluminium in the periodic table. This gap was filled up by gallium which was discovered later. The properties of gallium (Ga) were found to be similar to those of boron and aluminium.
4. Basic features intact : All the basic features of Mendeleev's periodic table are intact even today. Even when a new class of elements, i.e., noble gases, were discovered, they found place in a separate group called the zero group. The existing order of the periodic table was not at all disturbed.

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