Chemistry


Chapter : 1. Metals & Non Metals

Reduction with aluminium (thermit process or alumino-thermic process)

Reduction with aluminium (thermit process or alumino-thermic process)
Some metal oxides cannot be reduced satisfactorily by carbon. For them, aluminium, a more reactive metal, is used. The process is called thermic process or alumino-thermic process.
EXAMPLES :
(i) Manganese dioxide is reduced to manganese by heating with aluminium.
3MnO2 + 4Al → 3Mn + 2Al2O3
(ii) Ferric oxide (Fe2O3), is reduced by aluminium to free iron.
Fe2O3 + 2Al → 2Fe + Al2O3
(iii) Chromium sesquioxide is reduced by aluminium to chromium metal.
Cr2O3 + 2Al → 2Cr + Al2O3
In the thermit process, aluminium powder is mixed with metal oxide. A piece of magnesium is set alight to start the reaction. The aluminium reduces the oxide to free metal.
In case of iron oxide, iron is obtained in the molten state. (The mixture of iron oxide and aluminium powder is called thermite). The molten iron may be allowed to trickle down to weld two iron objects together. Cracked machine parts, railway tracks, etc., are joined by this method.

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